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There
exist a few companies in South Africa that refines
glycerine into either technical or pharmaceutical
grade from imported crude glycerine derived from
biodiesel plants overseas for about R3000 per ton.
The content of the imported glycerine is a minimum
of 80% glycerol, salt content of about 8%, MONG
(matter, organic, non-glycerol) content of 1% with
the remaining fraction being water.
The glycerine produced by South African biodiesel
producers using used cooking oil as feedstock is not
to the same standard as the imported glycerine
produced by the large commercial scale biodiesel
plants abroad. The local glycerine refineries
therefore do not want to process glycerine from the
South African biodiesel producers which consists of
methanol content from between zero and 30%, glycerol
content of as low as 20% up to 60%, soap content of
up to 60% and salt content of up to 8%.
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The
reason for the high soap content and the low
glycerol content is because used oil contains FFA
(free fatty acids) of up to 8% which is turned into
soap in the biodiesel (transesterification) process.
The pure glycerol produced in the biodiesel process
is stoichometrically about 10% but the actual crude
glycerol by-product is between 12% and 25% of the
biodiesel mass due to the salts, soaps and methanol
present in the crude glycerol.
The main drive behind this initiative is to absorb
the low quality crude glycerine produced by used
cooking oil plants and produce pharmaceutical grade
glycerine.
BIONEER has developed a process
to purify crude glycerol into 98% pure technical
grade glycerol!
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